Jumat, 19 Mei 2017

Explanation of hydrocarbons by Nina Nirwana

link youtube video :



Definition
         Definition of Hydrocarbons. Hydrocarbons are compounds consisting of carbon atoms (C) and hydrogen atoms (H). All hydrocarbons have carbon chains and hydrogen atoms binding these chains. For example, if the open carbon chain is called an aliphatic carbon compound such as alkane, alkene and alkaline hydrocarbons while the carbon chain is closed, it is called an alicyclic carbon compound such as cyclopentane and aromatic compounds such as benzene compounds. The carbon atom (C) with atomic number 6 has the electron arrangement K = 2 and L = 4. Carbon atoms have 4 valence electrons and can form four covalent bonds. For example, a CH4 (methane) molecule that has a fairly simple diagram below.

Classification of Hydrocarbons
The hydrocarbon classifications grouped by organic nomenclature are:

    Saturated / saturated hydrocarbons (alkanes) are the simplest hydrocarbons. These hydrocarbons are composed entirely of single bonds and bonded with hydrogen. The general formula for saturated hydrocarbons is CnH2n + 2. Saturated hydrocarbons are the main compositions of fossil fuels and are found in both straight and branched chains. Hydrocarbons with the same molecular formula but different structural formulas are called structural isomers.
    Unsaturated / unsaturated hydrocarbons are hydrocarbons having one or more double bonds, both duplicate and triplicate. Hydrocarbons having a double bond are called alkenes, with the general formula CnH2n. A hydrocarbon having a triple bond is called an alkene, with the general formula CnH2n-2
    Cycloalkanes are hydrocarbons containing one or more carbon rings. The general formula for saturated hydrocarbons with 1 ring is CnH2n.
General characteristics

Since the molecular structure is different, the empirical formula between hydrocarbons is also different: the amount of hydrocarbons attached to the alkene and the alkalo must be less because the carbon atoms are double bonded.

The ability of hydrocarbons to bind to itself is called cata- tation, and causes hydrocarbons to form more complex compounds, such as cyclohexane or arenas such as benzene. This ability is obtained because the bonding characteristics among carbon atoms are non-polar.

In accordance with the theory of valence bonds, carbon atoms must satisfy the "4-hydrogen" rule which states the maximum number of atoms that can bind to carbon, since carbon has 4 valence electrons. Seen from these valence electrons, carbon has 4 electrons that can form covalent bonds or dativ bonds.

Hydrocarbons are hydrophobic and are included in lipids.


Some hydrocarbons are available in abundance in the solar system. The lake contains methane and liquid ethane have been found on Titan, Saturn's largest natural satellite, as stated by the Cassini-Huygens Mission.

Using

Hydrocarbons are one of the most important sources of energy on earth. The main use is as a fuel source. In solid form, the hydrocarbon is one of the asphalt-forming compositions.
Hydrocarbons were once used for the manufacture of chlorofluorocarbons, a substance used as propellant in mosquito spray. Currently chlorofluorocarbons are no longer used because they have an adverse effect on the ozone layer.

Methane and ethane are gaseous at room temperature and are not easily liquefied by pressure alone. Propane is easier to melt, and is usually sold in tubes in liquid form. Butane is very easy to melt, making it safer and often used for cigarette lighters. Pentana is clear liquid at room temperature, usually used in industry as wax and fat solvent. Hexane is usually also used as a chemical solvent and is included in the composition of gasoline.

Hexane, heptane, octane, nonana, decane, including with alkene and some cycloalkanes are important components of gasoline, naphtha, jet fuel, and industrial solvents. With increasing carbon atoms, linear hydrocarbons will have higher viscosity and boiling properties, with darker shades.
 



Jumat, 12 Mei 2017

LEARNING IMPLEMENTATION PLAN (RPP)



LEARNING IMPLEMENTATION PLAN (RPP)
School:
Subject: CHEMICAL
Class / Semester: X / 1
Allocation Time: 45 minutes (1 hour lesson)

A. Core Competence (KI)

KI 1: Living and practicing the religious teachings it embraces.
KI 2: Demonstrate honest, discipline, responsibility, caring (cooperative, tolerant, peaceful) behavior, courteous, responsive and proactive and show attitude as part of the solution to problems in interacting effectively with the social environment And nature and in placing ourselves as a reflection of the nation in the association of the world.
KI3: Understand, apply, analyze factual, conceptual, procedural based on curiosity about science, technology, art, culture, and humanities with the insights of humanity, nationality, state and civilization on the causes of phenomena and events, and Apply procedural knowledge to a specific field of study according to his or her talents and interests to solve problems.
KI4: Processing, reasoning, and recruiting in the realm of concrete and abstract realms related to the development of the self-study in the school independently, and able to use methods according to scientific rules.
Basic competencies
Indicator
3.7. Determine the interaction between particles (atoms, ions, and molecules) and their relation to the physical properties of matter
3.7.1. Describes the interaction between particles
3.7.2. Determine the types of interactions between particles
3.7.3. Connects the type of interaction between particles and the physical properties of matter
 4.7. Reasoning the properties of the substances around us by using the principle of interparticle interaction

4.7.1. Applying the properties of the substances around us based on the principle of interaction between particles
 
Basic competencies
Indicator
3.7. Determine the interaction between particles (atoms, ions, and molecules) and their relation to the physical properties of matter
3.7.1. Describes the interaction between particles
3.7.2. Determine the types of interactions between particles
3.7.3. Connects the type of interaction between particles and the physical properties of matter
 4.7. Reasoning the properties of the substances around us by using the principle of interparticle interaction

4.7.1. Applying the properties of the substances around us based on the principle of interaction between particles


C. Learning Materials
ü  Interaction between particles

ü   Facts
H2O boiling point high
Alcohol is low point and volatile
 
ü  Concept
Van der Waals Style
Hydrogen bond

ü   Procedural
Steps of demonstration activities

ü   Metacognitive
Application of interaction relationships between molecules and physical properties of substances in everyday life.

D. Learning Activities
Third Meeting: (45min)
Indicators of Competence Achievement
3.7.1. Describes the interaction between particles
3.7.2. Determine the types of interactions between particles
3.7.3. Connects the type of interaction between particles and the physical properties of matter
3.7.4. Applying the properties of the substances around us based on the principle of interaction between particles
         
A. Introduction Activity (5 minutes)
• Berdo'a (religious)
• Checking students' / introductions (discipline)
• Asking students-with a focus on the unexpected / which the previous meeting was also not present. (Caring, empathy).
• Teacher asks, How many kinds of interactions between particles? (Answer: there are two, namely the hydrogen bond and the Van der Waals force
• What if the alcohol is stored in a yap and open bottle? (Answer: alcohol will evaporate)
• The teacher conveys the competencies to be achieved and the benefits in daily life.
• Teachers convey the scope of material and activities achieved (interactions between molecules and physical properties of substances by demonstration
• The teacher conveys the technique and scope of the assessment

B. Core activities
The steps of learning activities as follows:

No

Syntax / Learning Stages

Description of Learning Activity
(1)
(2)
(3)
1





2












3




4





5





6



Stimulation (giving stimulus);





Problem Statement (identify problem)











Data Collecting (collecting data);




Data Processing (processing data);





Verification (verify);





Generalization (conclude);

1. Mendemontrasikan water and alcohol are heated to boil with the same volume




2. It is expected that students will appear questions from learners can explain:
- Why Alcohol boils faster
From the water
- Why the volume of alcohol decreases
More than water
- Determine the forces between the inner molecules
Water and alcohol compounds



3. Students seek information and collect data about the interaction relationship between molecules with boiling point


4. Perform data processing through discussion.





5. Compare the results of the discussions between groups to classify and analyze and the interaction relationship between molecules with boiling points


6. Learners conclude the discussion on the problems in the daily life of the interaction between molecules with boiling point





Apply the results of the discussion in
       everyday life
 
A. Closing Activity

• Teachers and learners make inferences about interactions between molecules
• Teacher does reflection and feedback on process and learning outcomes
• Teacher provides evaluation and assignment
• The teacher informs the material that you will be studying in future meetings
E. Assessment technique
1. Assessment of Attitude:
A. Observation

2. Assessment of Knowledge
A. Assessment Technique: written test
B. Problem form: description
C. Assessment instrument: attached
3. Skills Assessment
Project: create a molecular model using materials in the environment

F. Media / tools, Materials, and Learning Resources
1. Media / tools: Laptop / LCD, beaker, Bunsen burner, triple + asbestos base
2. Material: H2O, alcohol
3. Learning resources: Chemistry Book Class X

Attachment:
1. Lesson learned
2. Knowledge Assessment Instrument
3. Observation assessment instrument
4. Skills Assessment Instrument


Appendix 1.
LEARNING MATERIALS

Subject: Chemistry
Class / Semester: X / 1
SKL: Have factual, conceptual, procedural, and knowledge
Metacognitive in science, technology, art, and culture
With the insights of humanity, nationality, statehood, and
Civilization-related causes and effects of phenomena and events.
Basic competence: 3.7. Determine the interactions between particles (atoms, ions, and molecules) and
Its relation to the physical properties of the substance
4.7. Reasoning the properties of the substances around us by using them
Principles of interparticle interaction.
Time Allocation: 3 hours Lesson

Indicators of Competence Achievement :

4.7.1 Explain the interaction between particles
4.7.2 Determine the types of interactions between particles
4.7.3 Connects the type of interaction between particles and the physical properties of matter
4.7.1 Apply the properties of the substances around us based on the principle of interaction between particles


Molecular Style:

Types of intermolecular forces that exist between molecules Intermolecular forces

Electrostatics

Up until now, we have just discussed attractions between molecules in the area of the covalent bond.  Here, atoms within a molecule are attracted to one another by the sharing of electrons.  This is called an intramolecular force.
We know how the atoms in a molecule are held together, but why do molecules in a liquid or solid stick around each other? What makes the molecules attracted to one another?  These forces are called intermolecular forces, and are in general much weaker than the intramolecular forces.
We have, however, already discussed a very strong type of  force that is responsible for much of chemistry - electrostatics. The attraction of a positive charge with a negative charge is the force that allows for the structure of the atom, causes atoms to stick together to form molecules; both ionic and covalent, and ultimately is responsible for the formation of liquids, solids and solutions.


London dispersion forces

The forces that hold molecules together in the liquid, solid and solution phases are quite weak.  They are generally called London dispersion forces.
We already know that the electrons in the orbitals of molecules are free to move around.  As such, if you would compare a "snapshots" of a molecule at an instant in time, you would see that there would be slightly different charge distributions caused by the different positions of the electrons in the orbitals.  Just how much difference one sees as a function of time is based on the polarizability of the molecule, which is a measure of how well electrons can move about in their orbitals.  In general, the polarizability increases as the size of the orbital increases; since the electrons are further out from the nucleus they are less strongly bound and can move about the molecule more easily.
Given that two molecules can come close together, these variations in charge can create a situation where one end of a molecule might be slightly negative and the near end of the other molecule could be slightly positive. This would result in a slight attraction of the two molecules (until the charges moved around again) but is responsible for the attractive London dispersion forces all molecules have.
However, these London dispersion forces are weak, the weakest of all the intermolecular forces. Their strength increases with increasing total electrons.


Dipole-dipole attractions

What would happen if we had a beaker of polar molecules, like formaldehyde, 

In addition to the attractive London dispersion forces, we now have a situation where the molecule is polar.  We say that the molecule has a permanent dipole. Now, the molecules line up. The positive ends end up near to another molecule's negative end:
Since this dipole is permanent, the attraction is stronger.  However, we only see this sort of attraction between molecules that are polar. It is usually referred to as dipole - dipole interaction.  The strength of this attraction increases with increasing total number of electrons.


Hydrogen bond

Hydrogen is a special element. Because it is really just a proton, it turns out that it can form a special type intermolecular interaction called the hydrogen bond. If the hydrogen in a moleucle is bonded to a highly electronegative atom in the second row only (N, O, or F), a hydrogen bond will be formed.
In essence the three elements listed above will grab the electrons for itself, and leave the hydrogen atom with virtually no electron density (since it had only the one). Now, if another molecule comes along with a lone pair, the hydrogen will try to position itself near that lone pair in order to get some electron density back. This ends up forming a partial bond, which we describe as the hydrogen bond. The strength of this interaction, while not quite as strong as a covalent bond, is the strongest of all the intermolecular forces (except for the ionic bond).
A diagram of the hydrogen bond is here:
Could the CH2O molecule exhibit hydrogen bonding? The answer is no, since the hydrogen must be bound to either N, O, or F. Just having one of those species in the molecule is not enough.


Trends in the forces

While the intramolecular forces keep the atoms in a moleucle together and are the basis for the chemical properties, the intermolecular forces are those that keep the molecules themselves together and are virtually responsible for all the physical properties of a material. The intermolecular forces increase in strength according to the following:
London dispersion < dipole-dipole < H-bonding < ion-ion
Now, as these things increase in strength it becomes harder to remove the molecules from each other. Therefore, one would expect the melting and boiling points to be higher for those substances which have strong intermolecular forces. We know that it takes energy to go from a solid to a liquid to a gas. This energy is directly related to the strength of attraction between molecules in the condensed phases. Since energy is directly proportional to the temperature, the above trends ought to hold true.
In addition, there are energies associated with making these phase transitions:
Each of these processes are endothermic, and scale with the magnitude of the intermolecular forces. Thus, as these intermolecular forces increase, so do the energies requires to melt, vaporize, or sublime (go from solid to a gas) a species.
Every substance also has an associated vapor pressure with it. The vapor pressure is defined to be the amount of gas of a compound that is in equilibrium with the liquid or solid. If the intermolecular forces are weak, then molecules can break out of the solid or liquid more easily into the gas phase. Consider two different liquids, one polar one not, contained in two separate boxes. We would expect the molecules to more easily break away from the bulk for the non-polar case. This would mean that, proportionately, there are more molecules in the gas phase for the non-polar liquid. This would increase the vapor pressure. Thus, unlike the physical properties listed above, the vapor pressure of a substance decreases with increasing intermolecular forces.
Now, as an example, we will plot vapor pressure as a function of temperature for three compounds:

Which molecule corresponds to which curve?
 


Appendix 2
InstrumentAssessment

KD
IPK
INDICATORS OF SOUL
3.7  3.7 Determine the interaction between particles (atoms, ions, and molecules) and their relation to the physical properties of matter








4.7
Me Reason for the properties of substances around us by using the principle of interparticle interaction.
3.7.1
Describes the interaction between particles

3.7.2
Determine the types of interactions between particles


3.7.3
Connects the type of interaction between particles and the physical properties of matter





4.7.1
Applying the properties of the substances around us based on the principle of interaction between particles

1.      1. Can explain interactions between molecules


2. Can Determine the types of interactions between molecules


3. Given an example of a learner's compound can connect the interactions between molecules and boiling points



4. Can provide examples of compounds in everyday life that have hydrogen bonds

About the description
1. Explain interactions between molecules?
2. Determine the interactions between molecules in alcohols?
3. Among the following compounds:
H2O, HCl, NH3, C2H5OH, Cl2, H2. Which one has van der waals style?
4. How is the interaction relationship between molecules with boiling point in a compound?
5. Give examples of the application of interaction relationships between molecules of action in everyday life?

KeyManagersandDrading Guidelines

No
Answer key
Score
Maximum score
1.
The force that occurs between molecules with each other
20
20
2.
In Alcohol Van der Waals style occurs
20
20
3.
C2H5OH, Cl2, H2
20
20
4.
If the interaction relationship between molecules gets stronger, then the boiling point is higher
20
20
5.
Petrol fuel has a weak Van der Waals style that easily burns and evaporates. We put gasoline in a closed place and away from the fire.
20
20
 

Guidelines for Scanning

VALUE = Actual / 10 x 100%

Appendix 3


Assessed Competencies: Assessment of Attitude (Observation)
Education units : ……………………………………..
Subjects : ……………………………………
Class / Semester / Lesson: ..........................................
Basic competencies :


Indicators:

Observation Format of Student's Scientific Behavior
Name of Student:
Attendee's number :
Material when observed:
Observation Date:

No.
Attitude
Criteria
Observation result
yes
no
1
Honest

1.   1. Reporting data in accordance with reality / in accordance with what is observed.
2. Convey opinions along with concrete data / observed data.


2
Discipline
1. Working on assignments according to the time set.
2. Collect the results of the work on time.


3
Responsible
1. Implement the task given by the teacher.
2. Complete the job thoroughly.


4
Environmental care
1. Clean the tables and chairs they occupy / tables and chairs are occupied in a clean / tidy.
2. Organize / re-place the tool / materials / books / other learning resources neatly or put back in the original place.


5
Cooperation
1. Appreciate the opinions of friends
2. Take part in group work


Maximum score


 

Note:
Value = Score acquired x 100%
                                      10

Appendix 4

Assessment of skills competencies
Education Unit:
Subject: Chemistry
Class / Semester: X / 1
SKL: Have factual, conceptual, procedural, and knowledge
Metacognitive in science, technology, art, and culture
With the insights of humanity, nationality, statehood, and
Civilization-related causes and effects of phenomena and events.
Basic competence: 3.7. Determine the interactions between particles (atoms, ions, and molecules) and
Its relation to the physical properties of the substance
4.7. Reasoning the properties of the substances around us by using them
Principles of interparticle interaction.
Time Allocation: 3 hours Lesson

Indicators of Competence Achievement :

4.7.4 Describes the interaction between particles
4.7.5 Determine the types of interactions between particles
4.7.6 Connects the type of interaction between particles and the physical properties of matter
4.7.2 Apply the properties of the substances around us based on the principle of interaction between particles



Discussion

Subject: Chemistry
Material: Intermolecular Style
Date and time :
Group name :
Members of the group :
Class:


No.
Aspect
Rating result


Good  (Score 3)

Enough (Score 2)

Less
(Score 1)

1.

2.

3.

4.

5.
Conformity Explanation and assignment / question

Go to the extent of the Material

Delivery Technique Description / answer

The cohesiveness of the Group members

Punctuality



 

Screening Guidelines
Score
Value
1 - 5
Less

6 - 10
Enough

10 - 15
Good




 




Explanation of hydrocarbons by Nina Nirwana

link youtube video : https://www.youtube.com/watch?v=ROP-Q2SWdek Definition           Definition of Hydrocarbons. Hydroca...